通过有机配体界定的锌的磷酸化合物拓扑结构(晶体).pdfVIP

Inorg. Chem. 2005, 44, 6998−7008 Novel Zinc Phosphate Topologies Defined by Organic Ligands Jian Fan and Brian E. Hanson* Department of Chemistry, Virginia Polytechnic Institute and State Uni ersity, Blacksburg, Virginia 24061 Received March 1, 2005 Six new zinc phosphates [C H N ][Zn (HPO ) (H PO ) (C H N ) ]2H O (1), [Zn (HPO ) (C H N ) ]4H O (2), 18 20 4 4 4 4 2 4 2 18 18 4 3 2 4 4 4 18 18 4 3 2 [Zn (HPO ) (H PO )(C H N ) (C H N ) ] (3), [Zn (HPO ) (C H N )] (4), [Zn(HPO )(C H N )] (5), and [Zn - 3 4 3 2 4 22 22 8 0.5 22 24 8 0.5 2 4 2 18 16 4 4 18 14 2 2 (HPO ) (C H N )] (6) have been synthesized under mild hydrothermal conditions in the presence of 1,4-bis(N- 4 2 12 10 4 benzimidazolyl)butane (L1), 1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene (L2), 1,4-bis(imidazol-1-ylmethyl)naphthalene (L3), 9-(imidazol-1-ylmethyl)anthracene (L4), and 1,4-bis(1-imidazolyl)benzene (L5), respectively, and their structures were determined by X-ray crystallography. Compound 1 exhibits a unique inorganic motif of isolated 8-rings interconnected by L1. Compound 2, also formed from L1, contains a previously unobserved chain structure composed of edge-sharing 4-rings and 8-rings. Compound 3, prepared from L2, possesses an unusual one-dimensional framework, which is composed of vertex-sharing 4-rings and triple fused 4-rings. The inorganic portions of 4, 5, and 6 ea