温度对CdS纳米颗粒形状和光致发光特性的影响.pdfVIP

24 2 原 子 与 分 子 物 理 学 报 Vol. 24 No. 2 2007 4 JOURNAL OF AT OMIC AND MOLECULAR PHYSICS Apr. 2007 : 100003 4(2007) CdS 1 2, 3 薛洪涛, 赵普琴 ( 1. , 210003; 2. , 210009; 3. , 210093) : 采用反胶束法, 在常温和低温下( 接近零度) 合成了硅土包裹 CdS 纳米颗粒. 高分辨电镜表明常 温下合成 颗粒呈现直径小于5 nm 球形, 而在低温下出现了短棒形和长达微米量级 线形. 通过对实 验过程 分析表明: 不仅合成CdS 纳米颗粒溶液 浓度, 而且温度对CdS 纳米颗粒 形状产生了重要 影 响. 进一步研究了CdS 纳米颗粒 光致发光特性. : CdS 纳米颗粒; 形状; 温度; 光致发光 : 0472+ . 3 :A Effect of temperature on the shape of CdS nanocrystals and photolumi nescence properti es 1 2, 3 XUE Hongtao , ZHAO Puqin ( 1. Department of Applied Physics, Nanjing University of Post and T elecommunication, Nanjing 210003, China; 2. Department of Applied Physics, Nanjing University of T echnology, Nanjing 210009, China; 3. National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093, China) Abstract: Silicaovercoated CdS nanocrystals w ere synthesized by a reversemicelle method at different tem peratures. HRTEM images show that CdS nanocrystals prepared at room temperation are sphereshaped and below 5 nm in diameter, but the CdS nanocrystals prepared at zero become rodshaped and w ireshaped w ith a length of several micra . Analysis of experiment process show s that not only the monomer concentration but the growth temperature plays a key role for determination of the shape of CdS nanocrystals. Furthermore, w e study the properties of photoluminescence ( PL) of CdS nanocrystals. Key words: Nanocrystals,