AlCl_3MCM-41催化剂上桥式四氢双环戊二烯异构化反应.pdf

2010 Chinese Journal of Catalysis Vol. 31 No. 4 文章编号: 0253-9837(2010)04-0383-03 国际版 DOI : 10.1016/S1872-2067(09)60057-7 研究快讯: 383~385 AlCl /MCM-41 催化剂上桥式四氢双环戊二烯异构化反应 3 齐丽莉, 纪 敏, 王新葵, 贺 民, 蔡天锡 大连理工大学化工学院化学系, 辽宁大连 116012 摘要：分别采用介孔 MCM-41 和 SiO 为载体制备了固载化 AlCl 催化剂, 考察了其催化桥式四氢双环戊二烯异构化生成挂式四 2 3 氢双环戊二烯反应性能. 结果表明, 180 °C 时 AlCl /MCM-41 催化剂上挂式四氢双环戊二烯选择性可达 95.7%, 而在 AlCl /SiO 3 3 2 上仅为 86.3%. 采用 N2 吸附-脱附、Hammett 指示剂法、吡啶吸附红外光谱和化学分析等方法对催化剂进行了表征. 结果表明, AlCl3/MCM-41 催化剂较弱的表面酸性和一维孔结构有利于挂式四氢双环戊二烯的生成. 关键词：MCM-41; 硅胶; 固载化; 三氯化铝; 四氢双环戊二烯; 异构化 中图分类号：O643 文献标识码：A AlCl /MCM-41 as a Catalyst for Isomerization of Endo-tricyclodecane 3 * QI Lili, JI Min , WANG Xinkui, HE Min, CAI Tianxi Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China Abstract: The catalytic activity of AlCl3 immobilized on MCM-41 for the isomerization of endo-tricyclodecane to exo-tricyclodecane was compared with that of AlCl immobilized on SiO . At 180 °C, 95.0% exo-tricyclodecane selectivity was obtained over AlCl /MCM-41, 3 2