LY12铝合金的锰酸盐导电化学转化膜制备与表征.pdf

LYl2铝合金的锰酸盐导电化学转化膜制备与表征 吴友恒。黎学明。杨文静。高丽 (重庆大学化学化工学院，重庆400044) [摘 要] 探讨成膜机理。结果表明：当KMnO。的质量浓度为5g／L。Na。ZrF。的质量浓度为0．05g／I。。PH值2．0。温度65 ℃，转化时间60s、沸水后处理30min时，所制备的锰酸盐转化膜颜色呈金黄色。该膜层均匀、致密，主要成分为 滴法耐腐蚀时间达到57s，转化膜表面接触电阻仅为铝合金基体接触电阻的15．6％。 [关键词]铝合金；锰酸盐；转化膜；耐蚀性；导电性 [中图分类号-ITGl74．45l [文献标识码]A andCharacterizationfor ChemicaIConversionFiim Preparation Permanganate onLYl2Aluminum Alloy wU Li You-heng。LIXue-ming．rANGWen—jing，GAO of andChemical 400044，China) University，Chongqing (CollegeChemistry Engineering，Chongqing chemicalanversionfilmonLYl2alaminumwasstudied of alloy [Abstract]Prepartiontechnologypromanganate filmwere withmainsalt accelerator corrosionresistanceand ofconversion tested KMnO{and Na2ZrF6．The conductivity the testandthecontactresistance film andstructure by dropping method。respectively．Themorphology，composition SEM formationmechanismfor conversionfilmwas were f EDSandXRD．A permanganate pro— analyzedby possible of conversionbathis5 resultsshowthatthebest chemical 0．05 ZrF6， posed．The component g／I。KMnO‘andg／I。Na2 whilethe valueis2．0at65℃for60sandthetimeof treatmentis30minin water．Theisuni— pH post boiling layer formand is ofA1。O，Mnelements．