N掺杂TiO2SiO2双层中空微球的制备及可见光光催化活性研究.pdf

· 18· 材料导报B：研究篇 N掺杂Ti02／Si02双层中空微球的制备及可见光光催化活性研究。 张高文，杨侃，叶 莹，刘嘉宁 (湖北工业大学材料科学与工程学院，绿色轻工材料湖北省重点实验室，武汉430068) 摘要 以阳离子PS为模板，正硅酸乙酯和钛酸丁酯为前驱体，三乙胺为氮源，采用溶胶一凝胶法，通过层层静 TS双层中空微球的可见光光催化活性。结果表明，通过Si02和Ti02的交替包覆形成了双壳层结构，保持了中空微 10、500℃焙烧得到的双层中空微球可见光催化活性最优，2 h内亚甲基蓝几乎完全降解，同时中空微球在重复使用 过程中依然能保持较高的可见光光催化活性。 关键词 双层中空微球TiOzSi02N掺杂 中图分类号：0643 文献标识码：A andVisible of Preparation Ti02／Si02 LightPhotocatalyticPropertiesN-doped DoubleShellHollow Microspheres ZHANG Gaowen，YANGKan，YE Ying，LIUJianing ofMaterialsScienceand Provincial ofGreenMaterialsfor (College Engineering，HubeiKeyLaboratory LightIndustry， Hubei of 430068) UniversityTechnology，Wuhan Abstract were reactionand N-dopedTi02／Si02(N-TS)compositemierospherespreparedbysol-gel layer-by- methodwithcationic andtitanium electrostatic as silicate layer self-assembly polystyrenemicrospherestemplate．ethyl tetrabutoxideas as source．AndtheN-TSdoubleshellhollow with precursor，triethylaminenitrogen microspheres structurewerefabricatedaftercalcinatedatthe structureof was mescIporous hightemperature．Themicrospheres characterized laser sizeand instrument，SEM，XIm，Uv-Visandthevisiblecata— by particle potential