有机硅改性聚酯型水性聚氨酯整理剂的制备及应用.pdfVIP

绗?1鍗风5鏈 鍗版煋鍔╁墏 Vol.31No.5 2014骞?鏈 TEXTILE AUXILIARIES May2014 鏈夋満纭呮敼鎬ц仛閰瀷姘存€ц仛姘ㄩ叝 鏁寸悊鍓傜殑鍒跺鍙婂簲鐢 閭 杈夛紝閭㈠缓浼燂紝寰愭垚涔 (瑗垮畨宸ョ▼澶у绾虹粐涓庢潗鏂欏闄紝闄曡タ瑗垮畨 710048) 鎽 瑕侊細浠ュ紓浣涘皵閰簩寮傛鞍閰搁叝(IPDI)銆佽仛宸变簩閰镐箼浜岄唶-1,4-涓佷簩閱囬叝浜岄唶(PBA)銆佷簩缇熺敳鍩轰笝閰?DMPA)銆佹皑鍩虹娌?AEAPS) 涓轰富瑕佸師鏂?涔欓唶涓哄皝绔墏,鍚堟垚鑱氶叝鍨嬫敼鎬ф按鎬ц仛姘ㄩ叝涔虫恫(WPU).鐢ㄧ孩澶栧厜璋?FT-IR)銆佹帴瑙﹁銆佽€愭按鎬у強鏂寮哄姏娴嬭瘯瀵筗PU鐨勭粨 鏋勫拰鎬ц兘杩涜琛ㄥ緛.閲囩敤璇ユ暣鐞嗗墏瀵圭緤缁掗拡缁囩墿杩涜鎶楄捣姣涜捣鐞冩暣鐞?骞舵祴璇曞叾鎬ц兘.缁撴灉琛ㄦ槑,闅忕潃AEAPS鐢ㄩ噺鐨勫鍔?鑱氶叝鍨嬫按鎬 鑱氭皑閰殑鑰愭按鎬у緱鍒版敼鍠?缁廤PU鏁寸悊鐨勭緤缁掗拡缁囩墿鎶楄捣姣涜捣鐞冩€ц兘鎻愰珮1~2绾? 鍏抽敭璇嶏細鑱氶叝澶氬厓閱嘂 姘存€ц仛姘ㄩ叝; 姘ㄥ熀纭呮补; 鏀规€? 鎶楄捣姣涜捣鐞冩€ 涓浘鍒嗙被鍙耳 TQ314.24 鏂囩尞鏍囪瘑鐮? B 鏂囩珷缂栧彿: 1004-0439(2014)05-0039-04 Preparation and application of silicone modified polyester water-borne polyurethane SHAO Hui, XING Jian鈦僿ei, XU Cheng鈦僺hu (SchoolofTextileMaterials,Xi鈥瞐nPolytechnicUniversity, Xi鈥瞐n 710048, China) Abstract: The polyester water-borne polyurethane emulsions (WPU) were synthesized by the reaction of isophorone diisocyanate (IPDI), polyethylene-1,4-buthylene adipateglycol (PBA), 2,2-dimethylol propionic acid (DMPA) and amino-modified silicone oil (AEAPS) and terminated by alcohol. The structure and properties of WPU were characterized by infrared spectrum (FT-IR), contact angle, water resistance and breaking strength test. The cashmere knit fabrics were treated with WPU emulsions and their pilling resistance was tested. It was found that the water resistance of WPU was improved with the increase of AEAPS content. The pilling re鈦 sistance of the treated cashmere fabrics were improved by 1~2 level.