Mn、Li共掺ZnO稀磁半导体的制备与铁磁性研究.pdfVIP

Mn、Li共掺Zno稀磁半导体的制备与铁磁性研究／王庆等 ·9· Mn、Li共掺ZnO稀磁半导体的制备与铁磁性研究。 王庆，王成，伍双杰 (华中科技大学电子科学与技术系，武汉430074) 摘要 采用固相陶瓷烧结法制备了Mn、Li共掺的ZnO稀磁半导体材料，实现了室温铁磁性。分别用XRD、 xPS和VSM对各样品进行了结构测量和磁性能测量．分析了Mn、Li掺杂浓度对Zn()基稀磁半导体的影响。结果 表明，在相同的外磁场下。随着Mn掺杂浓度的增加．陶瓷的磁化强度增大。但较高的Li掺杂浓度可能会形成更多 填隙离子．减少空穴浓度。最终使材料的室温铁磁性变差。 关键词 氧化锌稀磁半导体固相反应法铁磁性 中图分类号：【)472 ofMnandLi ZnO Magnetic Codoped by Properity Systhesized Solid—stateReaction WANG ie Qing，WANGCheng，WUShuangj ofElectronics ofScienceand 430074) (Department ScienceTechnology。HuazhongUniversity Technology，Wuhan Al斌radMnLi ZnObulk were solid-state measurements codoped samplespreparedby reaction．Magnetic showthatall own at300K．Thestructureand werecharacterized ferromagnetism samples crystal magneticproperties byX-raydiffraction(XRD)spectrometer，X-rayphotoelectronspectrometer(XPS)andvibrating．samplemagnetometer resultsshowthat．whenmeasuredatthesarrle field，the isincreasing (VSM)，respectively．The applied magnetization withMnconcentration Li theinterstitial concentrationisincreased。moreLiionswilltake sites， increasing．When up be whichwillcausetheholecontenttO decreasedandmakethe weak． room-temperatureferromagnetism WOldS ZnO，dilutedmagneticsemiconductor。solid-state Key