Gemini表面活性剂的吸附自聚和性质.pdfVIP

216 2003 Gemini 1 2 2 1 , , , ( 1. , 100083; 2. , 100083) : Gemini 表面活性剂通常是由两( 或三) 条疏水链、两 个亲水基和 一个连接基组成的两性分 ( 离) 子, 与由 亲水基和 疏水基构成的 体表面活性剂分( 离) 子相比较, 在临界胶团浓度、界面 性质和溶解性等方面有着独特的性质。由于其电荷密度高, 临界胶团浓度低, 并且有很低的Krafft 点, 能在低浓度下与高碳烷烃形成超低界面张力, 在石油开发中有着很好的应用前景。详述了该类 新型表活性剂的吸附、自聚、性质, 比较了与 体表面活性剂的差别。 : Gemini 表面活性剂; 吸附; 自聚; 性质 : T Q 424. 2: A : 0367-6358( 2003) 04-0216-05 , - Ads rpti n Self assembly and Pr perties f Gemini Surfactants - 1 , 2, - 2, - 1 WANG Yue xing HAN D ng WANG H ng zhuang LU Yi qiang ( 1. D ep artme nt of Chemistry , B eij ing Unive rsity of S cience and T echnology , B eij ing 100083, China; 2. Research nst it ute of P etroleum E xp lor ation and D ev elop ment, EOR D ep ar tment , B eij ing 100083, China) Abstract: The m lecule ( i n) f Gemini surfactant c nsists f tw hydr ph bic chains and tw hy dr philic heads c njugated by a bridge unit . C mpar ed w ith c nventi nal m n -chain surfactant, Gemini surfactant dem nstr ates unique featur es in critical micelle c ncentr ati n, interface pr perty and s lubility in w ater. Because f its high charge density , l w CMC and l w Krafft p int, superl w interfacial tensi n is bserved f r its mixture with high carb n number paraffin at l w c ncentr ati n, dem nstrating great p tential in petr leum expl itati n. Gemini surfactant is review ed, including its ads rpti n, self-assembly and pr per- , - . ties and c mparis n is miade betw een m n chain surfactant and Gemini surfactant Key words : Gemini surfactant; ads rpti n; self-assembly; pr perty Gemini ( )