溶胶-凝胶法制备LiFePO4C及其电化学性能.pdf

第34卷第1期 矿 冶 工 程 V01．34№1 2014年02月 M田ⅧNGAND Febmarv2014 M咂TAI．I．URGICALENGD旺您RING 李华成1，钟胜奎1’2，李普良1，厉冯鹏2，王春飞1，陈南雄1 (1．中信大锰矿业有限责任公司，广西南宁530028；2．苏州大学沙钢钢铁学院，江苏苏州215021) 150．6 mAh／g；循环30次后容量为146mAh／g，容量衰减率为3．05％。 关键词：锂离子电池；正极材料；磷酸铁锂；溶胶-凝胶法；电化学性能 中图分类号：TM912．9 文献标识码：A doi：10．3969／i．issn．0253—6099．2014．01．028 文章编号：0253—6099(2014)0卜0103—04 andElectrochemical of Sol—GelMethod Synthesis Properties LiFeP04／Cby UHua-chen91，ZHONGSheng—kuil”，LIPu—lian91，UFeng-pen92，W_ANGChun．feil，CHEN Nan—xion91 (1．C妣D口脚ng胧ni昭觑dwt庇s厶mi删，№凡ning ．sDoc^删‰眈糟渺，．s砒ou215021，胁—gs“，醌iM) were method aIld Abstract：LiFeP04／Csamplessynthesizedbysol—gel usingFb(N03)3·9H20，NH4H2P04 LiOH·H20 asrawmaterialsand PEG一4000as andcarbonsource．The polyethylenedycol chelatingagent crystalstructure， andelectIDchemicalof werecharacterizedSEMand mo叩hology propertiesLiFeP04／C byXRD， tests．TheresultsshowedthatPEG一4000as andc曲onsourcemadetlle of ped-onnance chelatingagent s锄plebeing small sizeand distributed．711le sinteredforl8hat particle unifomdy LiFeP04／Csample 650℃presented optimal electrochemicalwiththeinitial and of152．7 and at perfomance cha碍e dischargecapacities mAI∥g 150．6 0．1C， mAh／g a of146