溶胶-凝胶法制备TiO2薄膜光催化特性实验研究.pdf

·40· 材料导报B：研究篇 溶胶一凝胶法制备Ti02薄膜光催化特性实验研究 代福，李宏业，李嘉琪，陈华亮 (五邑大学应用物理与材料学院，江门529020) 摘要 采用溶胶一凝胶实验方法，研究了Ti02薄膜厚度、退火温度及退火时间对薄膜晶相结构、表面形貌和光 催化性能的影响。结果表明，Ti02薄膜光催化活性随着薄膜厚度的增加而增加，当薄膜厚度为3层时，光催化活性 达到最大，层数超过3层时，薄膜的光催化活性随薄膜厚度的增加反而降低；当退火温度为550℃时，Ti02薄膜中出 现金红石相，质量分数为25．4％，此时的光催化效率最高；随着退火时间的延长，Ti02晶粒尺寸逐渐变大，光催化活 性逐渐减弱。 关键词TiOz薄膜溶胶一凝胶法旋涂法光催化特性 中图分类号：TB383文献标识码：A DOI：10．11896／j．issn．1005-023X．2014．16．010 onthe of Thin Ti02 ExperimentalStudy PhotocatalyticProperties Films Method PreparedbySol—gel DAIFu，LI Hongye，LIJiaqi，CHENHualiang of and 529020) (DepartmentAppliedPhysicsMaterials，WuyiUniversity，Jiangmen Abstract effectsof film and method，the TiOz annealing Byusingsol—gel thickness，annealingtemperature timeonthe structure，thinfilmsurface and werestudied．Theresults phase morphologyphotocatalyticproperties showed that，the ofTiOzfilmsincreasedwiththefilmthickness thefilmwas photocatalyticactivity increasing，when 3 the reachedma】(imumnumber，morethan3 of layers，thephotocatalyticactivity 1ayers。thephotocatalyticactivity thefilmsdecreasedwiththefilmthickness the was rutile increasing；whenannealingtemperature550℃．Ti02phase inthethinfilmwiththemassfractionof25．4％，whichshowedthe appeared