正己烷萃取-连续流动光度法测定含油废水中的氰化物.pdfVIP

第 24 卷 ，第 4 期 化学分析计量 Vol. 24 ，No. 4 68 2015 年 7 月 CHEMICAL ANALYSIS AND METERAGE Jul. 2015 doi ：10.3969／j.issn.1008–6145.2015.04.020 正己烷萃取 – 连续流动光度法测定含油废水 中的氰化物 孙娟，张燕，胡恩宇 ( 南京市环境监测 中心站 ，南京　2 10013) 摘要 建立在线蒸馏– 连续流动分析仪检测含油废水中氰化物的分析方法。水样在pH ＞12 的碱性条件下， 以正己烷为萃取溶剂两次萃取净化，去除废水中的油类干扰物。氰化物的质量浓度在0.005～0.500 mg ／L 范围内与 响应峰高呈良好的线性，线性相关系数大于0.999 ，检出限为0.000 9 mg ／L ；对水样进行4 个质量浓度水平的加标 n 回收试验，回收率在85.0% ～110.0% 之间，测定结果的相对标准偏差为2.3% ～5.6% ( =6) 。该方法样品前处理简单、 重现性好、检出限低，适用于含油废水中氰化物的测定。 关键词 正己烷；含油废水；连续流动光度法；氰化物 中图分类号 ：O657.3 文献标识码 ：A 文章编号 ：1008–6145(2015)04–0068–04 Determination of Cyanide in Oily Wastewater by Hexane Extraction and Continuous Flow Spectrophotometry Sun Juan ，Zhang Yan ，Hu Enyu (Nanj ing Environmental Monitoring Center Station ，Nanj ing 2 10013 ，China) Abstract　The distillation on-line continuous flow spectrophotometric method for the determination of cyanide in oily wastewater was established. Under the condition of pH12 ，the wastewater samples were extracted with hexane twice and cyanide from aqueous phase was measured by continuous flow analyzer. The mass concentration of cyanide was linear with corresponding peak height in the range of 0.005–0.500 mg ／L ，the correlation coefficient was more than 0.999. The detection limit of the method (LOD) was 0.000 9 mg ／L. The recoveries of the target compound ranged from 85.0% to 110.0% and the relative standard deviations was 2.3%–5. n 6% ( =6). The method has good reproducibility, lower detection limit, the pretreatmen