罗正鸿 本体共聚过程仿真.pdfVIP

!!!!!!! ! 研究简报 ! 多尺度作用的D / APAEDMS 本体共聚过程仿真 ! !!!!!! 4 罗正鸿 詹晓力 陈丰秋 阳永荣 （浙江大学化学工程与生物工程学系，浙江 杭州 310027 ） 关键词 氨取代基有机硅单体 八甲基环四硅氧烷 多 “弯管”流动模型 反应 扩散联合动力学 - 中图分类号 文献标识码 文章编号 （ ） TO 316 .3 A 0438 - 1157 2003 01 - 0131 - 04 MULTIDIMENSION BULK-COPOLYMERIZATION MODEL OF OCTAMETHYLCYCLOTETRASILOXANE AND AMINO-SILICONE MONOMER ， ， LUO Zhenghong ZHAN Xiaoli CHEN Fenggiu and YANG Yongrong （ ， Dep artment of Chemical and Biochemical Engineering ， ， ， ） Zhej iang Uniuersity Hangzhou 310027 Zhej iang China Abstract For high viscosity bulk-copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer，a ， multisyphon flow physical model was established .Based on the free volume and chemical reaction kinetic theories a new computational model was developed to simulate the multisyphon flow model . As to the new model ， the united influence of reaction and diffusion was reviewed and analyzed . The new model was used to simulate bulk- copolymerization of octamethylcyclotetrasiloxane and amino-silicone monomer and agreed well with the results . Keywords amino-silicone monomer，octamethylcyclotetrasiloxane，multisyphon flow model ，reaction-diffusion united ki- netics