壳聚糖壳聚糖季铵盐交联共混阴离子交换膜的制备与性能研究.pdfVIP

39 1 Vo.l 39 No. 1 2010 1 Applied Chem ical Industry Jan. 2010 / 凌敏, 李茂政, 廖有为 ( , 530004) : ) ) ) /, FT IR ; ; , , HACC 25% , 0. 2% 53. 10 M Pa 8. 40 MPa, . 4% , IEC 2 1. 97 mmol/g, 2. 7 8 # cm , 0. 91, 81. % : ; ; ; : O 3 . 1 : A : 1 71- 320 ( 2010) 01- 00 0- 04 Preparation and properties of chitosan/quaternized chitosan blend cross-linked anion exchange membranes L IN G M in, L IM ao-zh eng, L IA O You-w ei ( College of Chem istry and Chem ical Engineering, GuangxiUn iversity, Nanning 530004, Ch ina) Abstract: A novel anion exchange membrane w ith chitosan and quatern ized ch itosan has been prepared and the prmi ary structure characterization has been performed by FT IR. The influence of various ch itosan/ quatern ized ch itosan compositions and the amounts of glutaraldehyde on properties of ion exchangemem- branesw as d iscussed. The ion transference number and the selective permeability have been estmi ate by testing membrane potential method. Analysis of ch itosan/quatern ized ch itosan blend cross-linked mem- branes show the membrane has excellent electrochem ical properties, but poorm echan ical properties, high w ater content rate, low er select permeability. Amount ofHACC 25%, the tensile strength ofmembrane and w et membrane about 0. 2% m ixed membranes are 53. 10, 8. 40 MPa, w ater content is . 4%, IEC 2 1. 97 mmol/g, area resistance 2. 7 8 # cm , ion transference number and selective permeability 0. 91, 81. % respectively. K ey wo