季铵盐表面活性剂引起非水混合溶剂的分相.pdfVIP

理化学学报(Wuli Huaxue Xuebao) July Acta Phys. Chim. Sin., 2006, 22(7) ：845 850 845 [Article] 季铵盐表面活性剂引起非水混合溶剂的分相 金彦 赵剑曦 陈 吉吉 (福州大学化学化工学院应用化学系, 福州 350002) 摘要 当季铵盐表面活性剂在极性溶剂中具有合适溶解度时, 它可使该极性溶剂与另一种非极性溶剂形成的混 合溶剂自发分相, 形成稳定的两相界面. 借鉴表面活性剂双水相现象的概念, 这种现象被称为表面活性剂非水双 相(NSTP), 也可简称为双油相. 产生此种现象的原因被归结为季铵盐表面活性剂在极性溶剂中达到合适的溶解 度时, 从而逐出与之不亲合的非极性溶剂. 关键词： 双油相, 季铵盐表面活性剂, 溶解度 中图分类号： O647, O648 Phase Separation in Nonaqueous Mixed Solvents Induced by Quaternary Ammonium Surfactants LIU, Jin鄄Yan ZHAO, Jian鄄Xi CHEN, Zhe (Department of App lied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002 , P. R. China) Abstract When a quaternary ammonium surfactant has a suitable solubility in a polar solvent, it can induce the phase self鄄separation of mutually soluble polar and apolar mixed solvents and a stable interface between the two phases can be formed. This phenomenon was attributed to the quaternary ammonium surfactant reaching suitable solubility in the polar solvent and driving out a considerable part of the apolar solvent, in which the surfactant is insoluble. As a result, phase separation appears. Using aqueous surfactant two鄄phase as reference, we suggest that it be termed as nonaqueous surfactant two鄄phase (NSTP) and also as two oil phases for short. Keywords ：Nonaqueous surfactant two鄄phase, Quaternary ammonium surfactant, Solubility 两种不相 的高分子可使其水溶液自发分成两 自发分成