离子液体中制备无机材料.pdfVIP

第 2 1 卷 第 10 期 化 　学 　进 　展 Vol . 2 1 No . 10 2009 年 10 月 PROGRESS IN CHEMISTRY Oct . , 2009 离子液体中制备无机材料 赵海丽 　汤正新 　张庆国　尤景汉 　陈庆东 河南科技大学理学院　洛阳 471003 摘 　要 　离子液体作为潜在的“绿色”溶剂 ,具有许多传统溶剂无法比拟的优异性能 ,在有机合成 、催化 、 液液分离和萃取等领域引起了广泛的研究 。而在离子液体领域无机材料的制备是一个较新的发展分支 , 已 利用其合成出多种具有独特结构和性能的无机材料 。本文就离子液体在无机材料制备方面的应用及发展趋 势进行了综述 。目前 ,对于制备无机材料 ,离子液体主要是作为电解液 、表面活性剂或溶剂 ,本文介绍了其在 应用中的优缺点 。并指出该领域未来的发展趋势是离子热合成和集模板溶剂反应物于一身的离子液体 反应 。 关键词 　离子液体 　无机材料 　离子热合成 　反应性离子液体 中图分类号 : O6454 ; O6114 ; TB383 　文献标识码 : A 　文章编号 : 1005281X 2009Inorganic Synthesis in Ionic Liquids Zhao Haili 　Tang Zhengxin 　Zhang Qingguo 　You J inghan 　Chen Qingdong The School of Science , Henan University of Science and Technology , Luoyang 471003 , China Abstract 　As a potential “green ”solvents , roomtemperarture ionic liquids RTILs have received much attention , and significant progress has been made in their applications for organic synthesis , catalysis , liquidliquid separations ,and extractions. However ,inorganic synthesis is a relatively new branch in the ionic liquid community which shows that ILs have great advantage over the traditional solvents in the synthetical process and provide a new route for inorganic synthesis. In recent years ,a number of inorganic materials with unique structures and properties have been synthesized from ionic liquids. This paper reviews the status and application of ionic liquids in the inorganic synthesis. Inoic liquids at present are mainly used as electrolytes , surfactants or solvents ,the advantages and disadvantages of ionic liquids in the application are analyzed . Ionothermal synthesis and allinone ionic liquids are the development trends in the synthesis of inorganic materials in the future . Key words 　ionic liquids ILs ; inorganic materials ; 　ionothermal synthesis ; 　allinone ionic liquids Contents 1 　引言 1 　Introduction 无机材料 ,尤其是纳米材料和介孔材料 , 由于在 2 　Ionic liquids as electrolytes 微电子学 、光学 、电磁学 、