预炭化时间对煤基活性炭孔结构及电化学性能的影响.pdfVIP

网络出版时间：2013-06-26 08:39 网络出版地址：/kcms/detail/11.3676.TD0839.011.html 煤 质 技 术 预炭化时间对煤基活性炭孔结构及电化学性能的影响 裴卫兵,邢宝林,黄光许,张传祥 (河南理工大学材料科学与工程学院,河南 焦作摇 454003) 摘要:以太西无烟煤为前驱体,KOH为活化剂制备煤基活性炭,考察了预炭化时间对煤基 活性炭孔结构及电化学性能的影响。 结果表明,随着炭化时间的增加,活性炭吸附量先增大 后减小,活性炭的比表面积、总孔容先增大后减小,中孔孔容逐渐减小;在预炭化温度800 益, 炭化时间6 h,KOH与太西无烟煤质量比为2颐1,活化温度800 益的条件下可制备比表面积为 2 3 1409 m / g,总孔容为0郾5284 cm / g,中孔率为6郾25%的煤基活性炭。 电流密度为50 mA/ g 时, 炭化6h制备活性炭的比电容最大为127 F/ g,电流密度增大至2500 mA/ g 时,比电容为84 F/ g, 容量保持率达到66郾1%,经过1000 次循环充放电后,其容量仍保持93郾6%。 关键词:炭化时间;煤基活性炭;电化学性能;比表面积;孔容 中图分类号:TD849;TQ351摇 摇 摇 文献标识码:A 文章编号:1006-6772(2013)03-0042-04 Influence of carbonization time on pore struture and electrochemical performance of coal鄄based activated carbon PEI Weibing,XING Baolin,HUANG Guangxu,ZHANG Chuanxiang (School of Material Science and Engineering,HenanPolytechnic University,Jiaozuo 454003,China) Abstract:Coal鄄based activated carbons as supercapacitor electrode materials were prepared from Taixi anthracite with KOH as activator.The pore structure and electrochemical performance of activated carbon were characterized by adjusting carbonization time.As prolonging carbonization time,the adsorption quantity,specific surface area and total porevolumeof activatedcarbonincreasefirst,then decrease.Theporevolumeof mesoporegradually decrease. When the precarburization temperature and time is 800 益 and 6h,the weight ratio of KOH to coal is 2,the activatied tempreture is 800 益,the specific surface,total pore volume,mesoporosity of prepared coal鄄based