芳香硝基化合物还原制备芳胺的研究进展尹静梅.pdfVIP

21 1 2010 1 CH EMICAL RESEARCH hxyj@ henu. edu. cn * 尹静梅 , 张 瑞, 贾颖萍, 崔颖娜, 周广运, 高大彬 ( , 116622) : . CO/ H O 2 . , , , . : ; ; ; ; :T Q 246. 3 : A : 100 - 1011(2010) 01- 0096- 06 Research Progress in Preparation of Aromatic Amine via Reduction of Aromatic Nitro Compounds * YIN Jing-mei , ZHAN G Rui, JIA Ying-ping, CU I Ying-na, ZHOU Guang-yun, GAO Da-bin ( L i aoni ng P rov i ncial K ey L abor at ory of B io- Org ani c Ch emist ry , D al i an Univ ers i ty , D al i an 116622, L iaoni ng , Chi na) Abstract:T he research progress in preparing aromatic amines v i a the reduction of aromatic nitro compounds is review ed. It is pointed out that the main preparation methods include catalytic hydrogenation reduction, reduction w ith CO/ H2 O, reduction w ith metal, reduction w ith sul- fide, reduction w ith metal hydride, electro-chemical reduction and photo-chemical reduction. Of these methods, reduction w ith hydrogen and reduction w ith hydration hydrazine, both be- longing to catalytic hydrogenation, are environmentally friendly and have a high yield and good selectivity, show ing promising prospect of application. Keywords: aromatic nitro compounds; reduction; aromatic amine; preparation; research pro- gress , , [ 1] . , 160 , 25 . , , [ 2] , . , ,