防止低合金高强度结构钢热镀锌层灰暗的措施.docVIP

防止Q345钢热镀锌出现灰暗镀层的措施 王艳宁1?,???梁中华2,???苗立贤1?,???史宪海3 （1．天津市工大镀锌设备有限公司，天津，300132；2.河南驻马店农机化研究所，驻马店，463000；3.河南驻马店管塔热镀锌厂，驻马店，463000） [摘要]：在热镀锌中，钢制构件中硅含量对镀层表面色差的形成和合金层厚度的影响比较明显。一般来说，在460oC温度下，Q235钢中硅含量在0.15-0.25wt％之间，适应热镀锌，表面不会出现灰暗镀层。而Q345钢则因硅含量在0.25wt％以上，在460oC温度下热镀锌，铁锌反应激烈，致使镀层表面灰暗，镀层超厚，粘附性差。为了避免因硅含量在0.25％以上热镀锌时镀层表面出现以上问题，本文通过以下四种方法试验研究了热镀锌温度在430-450oC范围内的镀层质量问题。（1）使用变频技术调整工件镀锌后分段从锌液中提升速度，设定在2-20米/分以内；（2）在锌液中添加少量的含铋、锡的锌基多元合金；（3）使用助镀剂除铁设备，使助镀剂中铁离子的含量在1g/L以下；（4）酸洗时避免过酸洗、重复酸洗等措施。结果表明，采取以上措施在430-450oC温度下热镀锌，可以控制镀层表面灰暗、镀层超厚等问题。 [关键词]：热镀锌；Q345；灰暗镀层；控制措施 Measure?to?prevent?Q345?from?dim?galvanizing?layer?during?hot-dip?galvanizing (Wang?Yan?Ning1,?Liang?Zhong?Hua2?,?Miao?Li?Xian1?,Shi?Xian?Hai3) (1.?Tianjin?Gongda?Galvanizing?Equipment?Co.,?Ltd?,?tianjin300132;2.Henan?zhumadian?research?institute?of?agricultual?mechanization,zhumadian463000;3.Henanzhumadian?hot-dip?galvanizing?of?tube?tower,zhumadian463000) Abstract:?In?hot?dip?galvanizing,?content?of?Si?in?steel?parts?have?an?obvious?effect?to?form?of?aberration?on?the?surface?of?zinc?layer?and?thickness?of?alloy?layer.?At?460°C,?0.15-0.25wt%?is?appropriate?content?of?Si?in?Q235?to?hot?dip?galvanizing,?and?gloomy?galvanizing?layer?won’t?come?into?being.?But?when?content?of?Si?in?Q345?is?beyond?0.25wt%,?Fe?and?Zn?react?drastically,?and?which?bring?about?gloomy?galvanizing?layer,?exceedingly?thick?galvanizing?layer,?and?bad?stickiness.?In?order?to?avoid?above?problems,?we?took?four?measures?and?researched?quality?of?galvanizing?layer??when?temperature?of?zinc?is?between?430°C?and?450°C.?(1)?Increasing?velocity?of?parts?out?of?zinc?after?galvanizing?by?converter?technique.?It?is?between?two?and?twenty?m/min.?(2)adding?a?small?quantity?of?zinc-base?complex?alloy?which?contains?Bi?and?Sn.?(3)making?content?of?Fe-ion?below?1g/L?by?the?equipment?which?removes?Fe?in?helping-galvanizing?reductant.?(4)?Avoiding?over?pickling?and?duplicate?pickling.?The?result?indicate?that?taking?such?measures?can?control?such?problems?as?gl