过渡金属配合物的合成、结构和性质研究.pdf

外光谱，紫外一-口J‘见光谱，热失重和循环伏安进行了表征。循环伏安曲线出现了三对 氧化还原峰，说明该化合物表现出氧化还原性，有望成为催化剂。 关键词：多金属氧酸盐；Dawson结构；多核配合物；有机一无机杂化；水热合成； 超分子 Il Abstr：act Thecurrent attentionand forcein the increasing powerfuldriving transition--metaloxideclusterschem on polyoxometalate(POM)chemistry,asearly istry,notly fromtheir in scienceand originate fascinatingpropertiescatalysis，medicine，material and alsofromtheir ofarchitecturestheir of photochromism，etc．butintriguingvariety diversity electronicstructuresand rateofPOMswithnovel topologies．．Recently,theemerging structures ismuchfasterthanever whichanotablesubsetofPOM—based reported before．，in clustersarethoseofthe stableclassicalDawsonstructuralskeleton very containingbridging atomsandwith structuresimilartomolecular shows oxygen cage·．type sieve．，whichhigh and in andmoreattentionwas tothis catalyticactivityselectivityorganicreactions，more paid field． Coordinationisoneofthemostactivemodem chemistry methodsmoreattentionto central the ofthe study paid single compounds，within-depth functionalmaterialswere interactionbetweenmetal biologicalsystem，new synthesized,，the ionsof and attractmoreandmoreattention．Themainreason polynuclearcompoundsligands isinthese