碱性硫脲浸金的研究现状与发展趋势刘有才.pdfVIP

2013 年 5 月 贵 金 属 May 2013 第 34 卷第 2 期 Precious Metals Vol. 34, No. 2 碱性硫脲浸金的研究现状与发展趋势 刘有才 1 1 1 * 1 1 1 1, 2 ，朱忠泗 ，符剑刚 ，李丽峰 ，林清泉 ，陈凯达 ，李志辉 (1. 中南大学 化学化工学院，长沙 410083 ；2 ．长沙矿冶研究院，长沙 410012) 摘 要：阐述了可能取代氰化浸金的高效、无毒碱性硫脲浸金的研究现状。相比酸性硫脲浸金，碱 性硫脲浸金具有溶金选择性好，溶液的再生及净化工序相对容易等优点。阐明了碱性硫脲浸金原理 及金在碱性硫脲溶液中的溶解机理，对碱性硫脲溶液中的稳定剂及氧化剂的选择做了详细探讨。最 后，指明了碱性硫脲浸金所取得的成果及需要解决的问题，并展望了其发展趋势。 关键词：冶金技术；碱性硫脲；机理；稳定剂；氧化剂；浸金 中图分类号：TF831 文献标识码：A 文章编号：1004-0676(2013)02-0078-04 Investigation Status and Development Trend of Leaching Gold with Alkaline Thiourea LIU Youcai1 1 1 * 1 1 1 1, 2 , ZHU Zhongsi , FU Jiangang , LI Lifeng , LIN Qingquan , CHEN Kaida , LI Zhihui (1. College of Chemistry Chemical Engineering, Central South University, Changsha 410083, China; 2. Changsha Research Institute of Mining and Metallurgy, Changsha 410012, China) Abstract: The recent research progresses of gold leaching with alkaline thiourea solution were summarized. This method is efficient, nontoxic and the most possible to substitute for dissolving gold with cyanide solution. Comparing with gold leaching in acidic thiourea solution, the advantages of gold leaching by alkaline thiourea solution are good selectivity, easier to regenerate and to purify the lixiviums. The principles and mechanisms of gold leaching with alkaline thiourea solution were stated. Stabilizers and oxidants of gold leaching with alkaline thiourea solution were discussed