Microstructure and Pseuapacitive Properties of Electrodes Constructed of Oriented NiOTiO2.pdfVIP
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Microstructure and Pseuapacitive Properties of Electrodes Constructed of Oriented NiOTiO2.pdf
Supporting Information
Microstructure and Pseudocapacitive Properties of Electrodes Constructed of
Oriented NiO-TiO Nanotube Arrays
2
1∗∗ 2∗∗
Jae-Hun Kim, Kai Zhu ∗∗ Yanfa Yan, Craig L. Perkins and Arthur J. Frank ∗∗
National Renewable Energy Laboratory, Golden, Colorado 80401-3393
TABLE S1: XPS-derived composition of Ni-Ti foil, annealed Ni-Ti foil, as-grown NT array, and
annealed NT array.
Atomic Concentrations (%)
Sample
Ti Ni O C F S N K
Sputtered Ni-Ti foil 50.1 49.9
Annealed Ni-Ti foila 32.9 3.0 52.4 10.4 0.3 0.4 0.6
As-grown NT array 26.8 8.2 45.6 11.4 7.3 0.8
Annealed NT arraya 19.6 17.0 47.8 14.0 0.7 0.9
a Annealed at a temperature of 600 oC.
XPS was used to characterize the composition and chemical states of the as-grown and annealed
films. Low energy resolution survey spectra were used to determine sample composition. Composition
was determined using standard sensitivity factors that, when applied to the sputter-cleaned foil substrate,
yielded values indicating that they were approximately correct. Table S1 lists the XPS-derived
composition of the metallic foil standard, annealed Ni-Ti foil, the as-grown NT film, and the annealed
NT film. Anodization of the Ni-Ti foi
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