Microstructure and Pseuapacitive Properties of Electrodes Constructed of Oriented NiOTiO2.pdfVIP

Microstructure and Pseuapacitive Properties of Electrodes Constructed of Oriented NiOTiO2.pdf

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Microstructure and Pseuapacitive Properties of Electrodes Constructed of Oriented NiOTiO2.pdf

Supporting Information Microstructure and Pseudocapacitive Properties of Electrodes Constructed of Oriented NiO-TiO Nanotube Arrays 2 1∗∗ 2∗∗ Jae-Hun Kim, Kai Zhu ∗∗ Yanfa Yan, Craig L. Perkins and Arthur J. Frank ∗∗ National Renewable Energy Laboratory, Golden, Colorado 80401-3393 TABLE S1: XPS-derived composition of Ni-Ti foil, annealed Ni-Ti foil, as-grown NT array, and annealed NT array. Atomic Concentrations (%) Sample Ti Ni O C F S N K Sputtered Ni-Ti foil 50.1 49.9 Annealed Ni-Ti foila 32.9 3.0 52.4 10.4 0.3 0.4 0.6 As-grown NT array 26.8 8.2 45.6 11.4 7.3 0.8 Annealed NT arraya 19.6 17.0 47.8 14.0 0.7 0.9 a Annealed at a temperature of 600 oC. XPS was used to characterize the composition and chemical states of the as-grown and annealed films. Low energy resolution survey spectra were used to determine sample composition. Composition was determined using standard sensitivity factors that, when applied to the sputter-cleaned foil substrate, yielded values indicating that they were approximately correct. Table S1 lists the XPS-derived composition of the metallic foil standard, annealed Ni-Ti foil, the as-grown NT film, and the annealed NT film. Anodization of the Ni-Ti foi

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