2-吡嗪羧酸Ni（Ⅱ）,Co（Ⅱ）和Cu（Ⅱ）配合物的合成、表征、电化学测试及其催化合成2H-吲哚[2,1-b]酞嗪三酮.pdfVIP

ChineseJournalofCatalysis36(2015)1101—1108 催化学报 2015年 第36卷 g7期 Ivlwv~．chxb．cn avaiiableat ．s鼙l囊臻擘dl毒≤耄eom 一 麓 强 _ 。 0 叠曩曩0一 ㈡ 曩一 誊 蓦 囊嚣曩薯 曩 一 舞 一 _ ~囊rect瞧 一■ …¨一曩 曩 曩曩 一曩薯 一 |川 ■ journa| m謦p霉e羲www鼍e}se}e；eom／l Ie／hje Article Ni{ll}，CoO1)，andCu{l1)complexesincorporating 2-pyrazinecarboxylicacid：Synthesis，characterization， electrochemicalevaluation，andcatalyticactivityforthesynthesisof 2H-indazolo[2，1一b]phthalazinet‘riones BehnazAfzalian，IoelT．Magueb，MaryamMohamadia,S．YousefEbrahimipourc,， BehjatPouramiri，EsmatTavakolinejadKermani aDepartmentofChemistry,PayamNoorUniversity(PN 19395—4697Tehran,lran bDepartmentofChemistry,TulaneUniversiyt,NewOrleanLA70118,USA cDepartmentofChemistry,FaculytofScience,ShahidBahonarUniversiytofKerman,Kerman,lran A R T IC L E IN F 0 A B S T R A C T Arffclehistory： Three complexes conatining 2-pyrazinecarboxylate (pzca一)， including fNip【zca)2[H20]2】， Received11Ianuary2015 c【o(pzca)2[H2O)2】and[Cu(pzca)2(H20)2]，havebeensynthesizedandcharacterizedusingphysico。 Accepted10February2015 chemicalandspectroscopicmethods．Furthermore，thestructureofeachcomplexwasdetermined Published20July2015 bysingle-crysatlX—raydiffraction．Allthreecomplexeshavean octahedralgeometry,wherethe metalion chelatedby twocarboxylateoxygens，twoni~ogenatomsbelongingtopyrazinicacid