硼氢阴离子交换树脂的制备及其对羰基,酰氯化合物的还原.pdfVIP

维普资讯 有 化学 YOUJIHUAXUE．1989，，，521～526 研究两报 硼氢明离子交换树脂的制备及其对羰基、酰氯化合物的还原 l_ 一 。 P ．Hodge**、 陈零威 ·、蒋济隆、刘慕 光 ¨、胡谋圳、卢 芊 胡．采源 … 一 一 (湖北大学化 学系，武汉 ，430062) PreparationofBorohydrideAnionExchangeResin(B~ ：)landReauc- ti0ns ofCarbonylGroup and AcylChloride Compounds P．Hodge ·， CHEN Jia—W ei*，JIANG Ji—Long， LIU M u—Guang“ ，HU M ow-Gang，LU Jun，HU Quan—Yuan 1= +蚕№ (DepartmentofChemistry．H “ University，430062Wuhan) AbstractIAn improved method ofpreparing Borohydride anion ExchangeResin (BER) haS been accOmplished by trestmentofquaternary ammonium typeanion eXChange resins with alkalineSoln．(unstired)．followed by washing on a column with NaBH~soln． The reduc- ttOn capadtjesoftheresinswerefound to be2．5～ 14 ． 6mmol／s．someOfthem we hi~her than valtm~reported be2ore．In general，thecapa cities ofallH ndsofresinsimmersed in al- ‘ katiWere higher than those uninunersed． Notonly carbonyicompo unds．tmtzlso．some,acyl chlorides could bc reduced to the~orresponding alcohols and alde h)desin satisfactory yields w ith these BER ．The resins COUld be recycled a few times without drastic decrease in redu· cing capa city． ‘ ， Descriptor：pojymersupportedreducingagent．quaternaryammonium type anion exchange resln．borohydride excha nge resin (BER) Gibson和’Bailey首次应用cl型季铵型强 8320型 GC仪，条件(a)：毛钿 管柱， 固定相 碱性 明离予交换树脂与 NaBH 交换， 制 备 了 DEGCt载气 ：氦，柱温 ；200CO。 100型 GC 硼氢街离早交换树脂 还原剂 (简称 BER) 。 仪，条件 (b)： 柱 3 Gas-Chrom-Qt 柱猛}