脂肪胺的生产和应用前景.pdfVIP

维普资讯 骺略晒 工艺， 脂 肪 胺 的 生 产 和 应 用 前 景 董 荣 ( ~ ,, 21403 舌 Abstract： Fattyamines8reagroupofiuterniediatesforcstlo~icand umphoteti~ surfa- ctants，as well asforsomeauxiliary agents·T featuresof：fatty amine industry are tke versa- ti1i¨ ofaminesa丑d derivatives，smal1rateofproductio$lforeach andthe irm|l1tipurpase app[icati— ons．In Chinatfattyamjne industry started twenty ye8rsagoandnow stepsjnto a丑 importantpeti一 0d0fdeve[opmentbased on the factsasfolIows：(1 Therate ofcationic and amphoteric sarfaetants isonly 2～3 ofthe orld production 8ndis3～^ ofthe tota1production ofsurfaetantsin China ‘ (2)ManYplantshave small capabilityand le{svarieties ofamines，(3)Sof8rthe fieldsofapp|i— cation Bre narrow andnt {ieldneedtobe opened． Amongthe technology ofproduction offatty ammes，Chiuahasdevelopedthecatalytic aminati。 on offattyalcoholsfortertiary aminesSRCCessfully．More than ten equipments hasbeenbuiltsince 1987and ithassupportedmarketdemandofChina．Recently somenew cata]ystsfor amination have been diseorved withboth higkconversion ‘99 )and selectj ity ‘98 )taswe11as better stubj’ litythan origin~ catalystswhichare esingin plants·The lavestigatim~ in ourlaboratory ha sshown thatwitk suchnt catalyst，the consumption of fatty toh may dlop s～ lO％ BⅡdthe purity。f am inem ay reach98 · Following are afev proposrlsfor fatty amine industry ofChina：(1)Facing an important period ofdevelomp entin 1990s!(2)F0rprimary and di-aminesitisnecessaryto introduceadvan ‘