氨系水溶性CdTe量子点的生长规律研究.pdfVIP

第36 卷第5 期 Vol.36 No.5 井冈山大学学报( 自然科学版) 2015 年9 月 Sep. 2015 Journal of Jinggangshan University (Natural Science) 37 井冈山大学学报( 自然科学版) 37 文章编号：1674-8085(2015)05-0037-06 氨系水溶性CdTe 量子点的生长规律研究 *林 谦，陈 盛 (福建师范大学福清分校海洋与生化工程学院，福建，福清 350300) 摘 要：在密闭容器的水相中以过量的NaBH4 保护合成的碲源与以巯基丙酸为稳定剂的镉溶液合成CdTe 量子点， 无需氮气保护，简化了合成工艺。合成的样品用透射电子显微镜（TEM ）对其形貌进行表征。用吸收光谱、荧光 光谱、红外光谱研究其光谱特征。考察了17 mmol 前驱浓度下的CdTe 在不同条件获得的量子点的发光特征。试 验结果表明：在碱介中控制不同的反应时间可获得发射绿光到红光区间的荧光波长可调的 CdTe 量子点，荧光光 谱半峰宽约37~60 nm 、峰形对称。量子点储藏半年后外量子效率仍达16.45%，发光效率高。通过实验建立量子 点的OA 和OR 生长模型，探讨和分析了CdTe 量子点的生长规律。 关键词：CdTe 量子点；水溶性；优化合成；生长规律；OA 和OR 模型 中图分类号：O657.3 文献标识码：A DOI:10.3969/j.issn.1674-8085.2015.05.008 GROWTH RHYTHM OF WATER-SOLUBLE CDTE QDS IN ITS OPTIMIZED SYNTHESIS * LIN Qian ，CHEN Sheng (School of Ocean Science and Biochemistry Engineering, Fuqing Branch of Fujian Normal University, Fuqing, Fujian 350300, China) Abstract: A simplified synthesis process of CdTe QDs was studied in this paper. First, the Te compound was synthesized in an airtight container with the protection of an excess of NaHB and the lack of N . Then it was 4 2 used to synthesize CdTe QDs in aqueous phase, with the MPA as a stabilizer. Based on this, the shape and appearance of CdTe QDs were characterized through TEM and the absorption, fluorescence and IR spectra were investigated. Through the experiment, the quantum dot emitting characteristics were studied from the reactions of the same concentrat