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《Keggin型硅钨酸盐[Cu(dap)2(H2O)][Cu(dap)2][Na(H2O)5]H[SiW11CuO39]amp;#183;H2O的合成与结构》.pdf
第23卷第6期 化学研究 中国科技核心期刊
2012年11月 CHEMICALRESEARCH hx妃@henu,edu.cn
andstructure
Synthesis
built
[Na(H20)5]H[SiWllCu039]·H20by
subunits
Keggin—typesilicotungstate
CHENLi Hui
juanl’2*,LUOJiel~,YUANJin91,LIyin91
(1. C^e,nzc4Z 475004,Hem,C^2nn;
Coz£eg£o,C赶emzsf7,&ndEngi月Per。ng,HP”“HL,nz口er5i£y,K丑i/0ng
CeӣPr 475004,HPnn,C^inn)
Z._rPnc^ingD,B口sicEzpPri研P川!,HenⅡn【肪i口Brsz眇,Kni^”g
novelthree substituted
Abstract:A dimensional(3一D)organicinorganichybridmono—copper
Keggin—type
of
the reaction
by hydrothermalNaloL』oa—SiW9
(1)(dap一1,2一diaminopropane)wasprepared
8 H—tetrazole~1一aceticacidand was
034]·1H20,CuCl2·2H2O,1 dap.As—synthesizedproduct
characterizedelemental and diffraction.
by analysis,infraredspectrometrysin91e—crystalX—ray
thatthemolecularstructural of1containsa substituted
Resultsindicate fragment mono—copper
Keggin—typep01yoxometalatesubunit[口一siwl【cuo朝]6+,one
andonelat—
cation,one proton
bridging[Cu(dap)2]2+cation,one[Na(H20)5]+cation,one
in
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