《Resolution of 3,3#39; -Dioxo-1,1#39; (3H,3#39; H)spirobi[isobenzofuran] -5,6,5#39;6#39;-tetracarboxylic acid and Optically active Polyimides thereof》.pdfVIP

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《Resolution of 3,3#39; -Dioxo-1,1#39; (3H,3#39; H)spirobi[isobenzofuran] -5,6,5#39;6#39;-tetracarboxylic acid and Optically active Polyimides thereof》.pdf

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《Resolutionof3,3amp;#39;-Dioxo-1,1amp;#39;(3H,3amp;#39;H)spirobi[isobenzofuran]-5,6,5amp;#39;6amp;#39;-tetracarboxylicacidandOpticallyactivePolyimidesthereof》.pdf

Chinese Chemical Letters Vol. 11, No. 12, pp. 2000 1077 Resolution of 3,3¢-Dioxo-1,1¢ (3H,3¢H)spirobi[isobenzofuran] -5,6,5¢6¢- tetracarboxylic acid and Optically active Polyimides thereof Fu She HAN, Jian Qiang QU, Xin ZHANG, Meng Xian DING, Lian Xun GAO * PCLCC, State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 Abstract: 3,3-Dioxo-1,1(3H,3H)spirobi[isobenzofuran]-5,6,5,6-tetracarboxylic acid 1 was resolved successfully and the corresponding optically active polyimides PI were synthesized. The properties of the optically active PI and the racemic one were investigated. The results showed that the specific rotation of (-)-PI was about two times to that of the (+)-PI, and the regularity of the optically active PI was higher than that of the racemic one. Keywords: Resolution, spirodilactone tetracarboxylic acid , optically active polyimide. Previously, we have reported a novel type of polyimides prepared from 3,3 -dioxo- 1 1,1(3H,3H)spirobi[isobenzofuran]-5,6,5,6-dianhydride 1a and a variety of diamines . 2 Considering that a spiral compound is planar asymmetry , we recently studied the resolution of 1, and thereof, synthesized the optically active polyimide