《Syntheses of Two Chiral Clusters [η5-C5H4C(NR)CH3]-RuNiM(CO)5(μ3-S) (R = NH-C6H3-2,4-(NO2)2, M = Mo, 3;M = W, 4) and the Single-crystal Structure of Cluster 3》.pdfVIP
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《Syntheses of Two Chiral Clusters [η5-C5H4C(NR)CH3]-RuNiM(CO)5(μ3-S) (R = NH-C6H3-2,4-(NO2)2, M = Mo, 3;M = W, 4) and the Single-crystal Structure of Cluster 3》.pdf
22 卷3 期 结 构 化 学 JIEGOU HUAXUE Vol. 22, No. 3
2003. 5 Chinese J. Struct. Chem. 301~304
5
Syntheses of Two Chiral Clusters [h -C H C(NR)CH ]-
5 4 3
RuNiM(CO) (m -S) (R = NH-C H -2,4-(NO ) , M = Mo, 3;
5 3 6 3 2 2
M = W, 4) and the Single-crystal Structure of Cluster 3
BIAN Zhi-Guo CHEN Yu-Gang YIN Yuan-Qi
(State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute
of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China)
LI Qing-Shan
(Research Institute of Element-Organic Chemistry, Nankai University , Tianjin 300071, China)
5
ABSTRACT The new chiral clusters [h -C H C(NR)CH ]RuNiM(CO) (m -S) (R = NH-C H -2,4-
5 4 3 5 3 6 3
(NO ) , M = Mo, 3; M = W, 4) were synthesized and the structure of cluster 3 was determined by
2 2
single-crystal X-ray analysis. Crystal data: C H O N MoNiRuS, M = 780.18, orthorhombic, space
23 16 9 4 r
group Pbca with the following crystallographic parameters:
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