《Synthesis and Crystal Structure of the Perchlorate Salt of Diprotonated 2,3-Di-2-pyridyl-5-nitroquinoxaline》.pdfVIP

21 卷6 期 结 构 化 学 JIEGOU HUAXUE Vol. 21, No. 6 2002. 11 Chinese J. Struct. Chem. 621~625 Synthesis and Crystal Structure of the Perchlorate Salt of Diprotonated 2,3-Di-2-pyridyl-5-nitroquinoxaline a , b b b b , c XU Qiang DU Miao GUO Ya-Mei BU Xian-He a(Department of Chemistry, Western Chongqing University, Chongqing 402168, China) b(Department of Chemistry, Nankai University, Tianjin 300071, China) c (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) ABSTRACT The diprotonated perchlorate salt of 2,3-di-2-pyridyl-5-nitroquinoxaline [C H N O ](ClO ) (CH OH)(C H OH) has been synthesized and characterized by elemental 18 13 5 2 4 2 3 2 5 analysis, IR and NMR spectra. X-ray diffraction analysis at room temperature indicates that the title compound (C H N O Cl , M = 608.34) crystallizes in triclinic, space group P î with a = 21 23 5 12 2 r 3 7.992(8), b = 12.82(1), c = 13.42(1) Å, a = 104.77(2), b = 97.84(2), g = 95.48(2), V = 1305(2) Å , 3