《Synthesis and Crystal Structure of [Ni(bdpm)2(OAc)]2(N3)2#183;5H2O (bdpm = Bis(3,5-dimethylpyrazol-1-yl)methane, OAc = CH3COO-)》.pdfVIP
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《SynthesisandCrystalStructureof[Ni(bdpm)2(OAc)]2(N3)2amp;#183;5H2O(bdpm=Bis(3,5-dimethylpyrazol-1-yl)methane,OAc=CH3COO-)》.pdf
25 卷9 期 JIEGOU HUAXUE Vol. 25, No. 9
2006. 9 Chinese J. Struct. Chem. 1115~1119
Synthesis and Crystal Structure of
[Ni(bdpm) (OAc)] (N ) ·5H O (bdpm = Bis(3,5-
2 2 3 2 2
dimethylpyrazol-1-yl)methane, OAc = CH3COO )
GAO Hong-Yana, b LING Yuna ZHANG Leia
a (School of Chemical and Energy Engineering, South
China University of Technology, Guangzhou 510640, China)
b
(School of Chemistry and Chemical Engineering,
Guangxi University, Nanning 530004, China)
ABSTRACT A Ni(II) complex [Ni(bdpm) (OAc)] (N ) ⋅5H O (bdpm = bis(3,5-dimethylpyrazol-
2 2 3 2 2
1-yl)-methane) was synthesized and characterized by elemental analysis, IR and single-crystal X-ray
diffraction. It crystallizes in the monoclinic system, space group P21/c with a = 18.630(2), b =
3
16.6624(19), c = 19.821(2) Å, β = 90.146(2)º, V = 6152.9(12) Å , Z = 4, C H N Ni O , M =
48 80 22 2 9 r
3 -1
1226.76, Dc
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