添加Si对A2B7型电极合金结构及电化学贮氢性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 406−414 Structures and electrochemical hydrogen storage performance of Si added A B -type alloy electrodes 2 7 1,2 1 1 1,2 1,2 2 Yang-huan ZHANG , Hui-ping REN , Ying CAI , Tai YANG , Guo-fang ZHANG , Dong-liang ZHAO 1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China; 2. Department of Functional Material Research, General Iron and Steel Research Institute, Beijing 100081, China Received 4 January 2013; accepted 6 September 2013 Abstract: In order to ameliorate the electrochemical hydrogen storage performance of La−Mg−Ni system A B -type electrode alloys, 2 7 a small amount of Si was added. The La Mg Ni Co Si (x=0−0.2) electrode alloys were prepared by casting and annealing. The 0.8 0.2 3.3 0.2 x effects of adding Si on the structure and electrochemical hydrogen storage characteristics of the alloys were investigated systematically. The results indicate that the as-cast and annealed alloys hold multiple structures, involving two major phases of (La, Mg) Ni with a Ce Ni -type hexagonal structure and LaNi with a CaCu -type hexagonal structure as well as one residual phase