Trich9551硫酸盐三价铬电镀工艺研究.docVIP

Trich9551硫酸盐三价铬电镀工艺研究 Trich9551硫酸盐三价铬电镀工艺研究 郭崇武，赖奂汶 （广州超邦化工有限公司，广东 广州? 510460） ? ??? [摘? 要]? 研究和制定了Trich9551硫酸盐三价铬镀铬工艺。镀铬速度快，0.055 ～0.075 μm/min， 镀层可连续增厚。镀液稳定，操作简单，容易控制。用250 mL霍尔槽，5 A电流施镀5 min，镀500张试片，镀液性能保持不变。温度升高，镀铬速度加快，但镀液的覆盖能力降低，电流增大，覆盖能力提高，pH 值3.0 ～ 3.6范围，镀液的性能较好。镀层质量优良，色泽美观，厚度能够达到0.3 μm以上。研究表明，Trich9551新工艺具有明显的优越性和较好的市场前景。 ??? [关键词]? 硫酸盐体系? 三价铬电镀? 新工艺? 镀铬速度? 耐腐蚀性 ? Researches on Trich9551 Technology of Sulphate Trivalent Chromium Plating ? GUO Chong-wu, LAI Huan-wen (Guangzhou Ultra Union Chemicals Ltd, Guangzhou? 510460, China) ? Abstract: Trich-9551 technology of trivalent chromium in sulphate system was reseached and established. Chromium plating rate of the new technology is rapider, which is 0.055 ~ 0.075 μm/min, and increase in thickness of chromium coatings is constinuous. Plating solution is stable, operation simple, and control of the solution easy. The plating solution still retains its primary performances after 500 test plates were electroplated with 250 mL Hull cell, during wich, one test plate was plated 5 min using 5 A electric current. The chromium plating rate increases with increase in temperature, but covering power of the plating solution decreases, and covering power increases with increase in electric current. The plating solution performance is finer under conditions of pH from 3.0 to 3.6. The chromium coating quality is excellent, color beautiful, and the thickness can exceeds 0.3 μm. Researches showed that Trich-9551 new technology of trivalent chromium plating has obvious superiority to others and better market prospects. Keywords: sulphate system; trivalent chromium plating; new technology; chromium plating rate; resistance corrosion 0? 前言 ??? 由于六价铬对环境污染严重，并且对人体有致癌作用，六价铬电镀已经受到了越来越严格的限制，业内人士正在积极开发三价铬镀铬[1]。 1975年英国Albright﹠Willson公司申请了Alecra-3000氯化物三价铬镀铬专利，三价铬电镀进入了实用阶段。但氯化物体系电镀时 在阳极上析出氯气，对环境和人体有害。1981年英国W. Canning公司开发了双槽硫酸盐三价铬电镀体系（W. Canning现已被麦德美收购），1990年代中期，开发使用了钛基涂膜阳极（DSA）系统，使硫酸盐三价铬镀铬从双槽变为单槽，操作简单易行，硫酸盐 体系进入了大生产阶段。2003年麦德美公司推出了硫酸