Performance of EDAB-HCI Acid Blended System as Fracturing Fluids in Oil Fields-论文.pdf

ENERGY,RESOURCESAND ENVIRONM ENTALTECHNOL0GY ChineseJournalofChemicalEngineering，22(2)202—207(2014) DOI：10．1016／S1004—9541(14)60028—8 PerformanceofEDAB-HCIAcidBlendedSystem asFracturingFluids inOilFields ZHAo Zengying(越增迎)，L Guocheng(吕国诚)’，ZHANGYihe(张以河)，LIAN iang(连胜江)andTIANNa(田娜)‘ Shengj Schoo1ofScience，NationalLaboratoryofMineralMaterials，ChinaUniversityofGeosciences(Bering)，Beijing 100083．China ResearchInsfituteofPetroleumExplorationandDevelopment，PetroChina，Beijing100083，China Abstract Duetothehighpriceandformationdamageoftheguargum rfacturingfluid，mna yoilfleldsaremore andmoreinterestedinsurfactantbasedfracturingfluids．Therheologica1propertiesoferucicamidedimethY1ami— dopropylbetaine(EDAB)一HC1acidblendedsystemanditssuitabilityasfracturingfluidwereinvestigatedinhtis work．TheeffectsofpH、concentrationofEDAB．na dtemperatureonhterheologica1propertiesoftheblendedsys— tem werestudied．Theresultsshow thatadditionofEDAB improvedtheviscosityofthesystem from lessthan10 mPa·stoabout400mPa．s．whichcouldretradtheacidrockreactiontoaboutonehalfat60。Candonequarterat 90。C comparingtostraightHClacid．suggestingthatthereissufficienttimefortheblendedfluidtoreactwim for— marionrockwhenitisusedasfracturingfluidinna oilfield．Coreflow testsdemonstratedmattheEDAB—acid blendedfluidcoulddivertitselfrfom highpemr eabilityformationcoretolow permeability one．thusensuring properacidplacementinthetragetreservoirs． Keywords viscosity,surfactants，viscoelasticfluids，rheology 1 INTRODUCTION inwater．Th eEDAB—HC1blendedsystem comprisedof EDAB surfactantwithmasscontentrfom l％ tO7％ ViscoelasticsurfactantfVES)aqueoussolutions (similarlyhereinafter)．HClwithmassconcentTation