Houston_Igor.ppt.pptVIP

Some new compounds for medicine and industrial applications Dr hab. In?. Prof. PS S?awomir M. Kaczmarek Institute of Physics Optoelectronics Head, cooperation: Department of Chemistry Szczecin University of Technology Poland 2. Synthesis and characterization of new compounds Ni2CrV3O11, Mg2CrV3O11 and Zn2CrV3O11 MSc A. Worsztynowicz * Contents Macrocyclic compounds C27H24N4O3Cl3Gd, C27H24N4O3Cl3Gd (33TGd, 33THo) Macrobicyclic C39H51N8O3 (1T) - cryptand M2CrV3O11-x (M=Mg, Ni, Zn) compounds Li2B4O7:Co single crystals SrxBa1-xNb2O6 pure and doped with Cr single crystals 1. Microcyclic compounds. MSc G. Leniec Taking into account their structure one can recognize a lot of groups, e.g.: Ligand Complex Podant Podate Coronant Coronate Cryptant Cryptate Carcerant Carcerate Among them macrocyclic and macrobicyclic compounds arises showing tendency to form complexes with cation of alkali-metals and rare-earths. The complexes are able to dissolve ionic compounds and inorganic salts in non-polar solvent. Synthesis of the compounds is very important in applied chemistry: separation of selected metals and supramolecular devices, fluorescent probes in biological systems, luminescence labels (detection of small amounts of biomolecules that can tell about the physical state of a patient) and medical diagnostics, treatment of arteriosclerosis, radioimmunology, as the contrast medium, as the synthetic enzyme to split chain of the nucleic acid [1, 2]. Gadolinium and other rare-earth elements are used as gasoline-cracking catalysts, polishing compounds, carbon arcs, and in the iron and steel industries to remove sulfur, carbon, and other electronegative elements from iron and steel. In nuclear research, the rare-earths are usually used in the form of oxides. An important application of gadolinium, because of its extremely large nuclear cross-section, is as an absorber of neutrons for regulating the control l