芳并多元含氮杂环骨架地构建.pdf

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芳并多元含氮杂环骨架地构建.pdf

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Abstract ontheconstructionofthefused skeleton the Thethesisfocuses through aza-polycyclic intramolecularSchmidtreactionof chlorideswith azides．Theinnovationoftheresearch acyl alkyl key the oftheSchmidtreactionof the ions istocontrol chlorides，andN-acyliminium migrationgroup acyl methineoverthe withthe isaddressed ofa group methylenegroup designed through1,2一migration ofthe ionswitharomaticis (o．azido acids．Theintramolecular carboxylic captureN-acyliminium rings carbonatomandenhRacestheatom oftherelated avoidsthe10SSof documented，which efficiency conversion．Thedissertationis the three composedby followingparts： mmefn-st classicSchmidtreactionof acidswith acidhasbeen part,the carboxylic hydrazoic shorter ofthesubstrates．The areone—carbonhomologs possible reviewed．Generally，theproducts andthe oftheconversionareintroducedhere． mechanism process of chloridesis Schmidtreactionof IIlmesecond Schmidtreaction part,the acyl presented．The chlorideswith azides ionintermediateshasbeen and acyl alkyl throughN·acyliminium designed havebeenconvertedtothe benz