Biodiesel Production by Enzymatic Catalysis Process Using Two Analytical Ways: Gas Chromatography and Total Glycerol Determination.pdfVIP
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Biodiesel Production by Enzymatic Catalysis Process Using Two Analytical Ways: Gas Chromatography and Total Glycerol Determination.pdf
J.Chem.Chem.Eng.8(2014)717-726
BiodieselProductionbyEnzymaticCatalysisProcess
UsingTwoAnalyticalWays:GasChromatographyand
TotalGlycerolDetermination
IgnacioContrerasAndrade,JonathanParraSantiago2Jos6RicardoSodr6,JosephSebastianPathiyamattom4and
,
CarlosAlbertoGuerrero.Fajardo。
』.DoctorChemicalEngineering,UniversidadAut6nomadeSinaloa,Culiacan80040,Mdxico
2.ChemicalEngineeringfC).UniversidadNacionalde Colombia,Bogotd11001Colombia
3.CoordinatorofthePostgraduateProgram inMechanicalEngineering,PonqficalCatholicUniversityofMinasGerais,Belo
Horizonte30130,Brazil
4.CenterforEnergyResearch,UniversidadNacionalAutonomadeMdxico,Temixco62580,Mdxico
5.ChemicalEngineeringandMechanical,UniversidadNacionalde Colombia,Bogot611001,Colombia
Abstract:Currently.biodieselispresentedasoneofthebestalternativesforgraduallyreplacingtheuseoffossilfuels.butithas
somefactorsthatmakeiteconomicallyimpracticalifitdoesnothaveagovernmentsupport.Forhtisreason.researcheffortsfocused
onthisareahavebeenresponsibleofroptimizingtheprocessofbiodieselproductionbydifferentcatalyticroutestoachievegreater
effi ciencyatalowercost.Inthiscase,htebiggestproblem hasbeenhtehighcostgeneratedbyaninvestigation,whichinmany
occasionsishtemainfactortodecideifaninvestigationcouldbecarriedout.Tryingtoreducehtesecosts.inhtecurrentstudy.we
areusingatechniqueofglycerolquantificationbyvolumetricmethodsandcomparingobtainedresultswiththechromatographic
method.whichisconventionallyusedandcomparativelymuchmoreexpensive.Biodieselemployeewasobtainedbyanenzymatic
catalysisprocessvaryingoneofthreeprocessvariables:oil:alcoholmolarratio,temperatureandproportionofcatalyst.Thenumerical
differencesobtainedbetweenhtetwoquantificationmethodsgeneratedrelativeerrorslowerthan l0%.resultinginsomeoccasions
lowerthan 1%.Bygaschromatographynaalysishtebestyieldwasobtainedatthesameconditionsofthevolumetricmethod.a
temperatureof45。C,anoil:alcoho1ratio 1:4and8wt.% ofcatalyst
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