界面分子组装-中科院.ppt

Conductivity of the ultrathin films Figure 2. UV-Vis spectra of (a) the solution of TPPS and 20-layer LS films of amphiphiles (b) ODA (c) CTAB (d) DOAB with TPPS transferred at 30mN/m CD spectra of 20-layer LS films of (a) ODA (b) CTAB (c) DOAB with TPPS transferred at 30mN/m. * * 界面分子组装 中国科学院化学所 刘鸣华 liumh@iccas.ac.cn 胶体与界面化学 分散体系 界面现象 The term ‘‘self-assembly’’ has been applied to multimolecular systems to differentiate them from simpler host–guest complexes. It is a historical fact that colloid chemistry had been involved with self-assembly for decades before the coining of the word ‘‘supramolecular.’’ Yet the word ‘‘colloid’’ seldom if ever appears even in the most prominent reviews of supramolecularity and self-assembly. Poor colloid chemistry! For decades, colloid chemistry was a stepchild of physical chemistry as the attention and glory focused on quantum mechanics. When (finally!) self-assembly was accepted into the forefront of science, supramolecular chemistry immediately embodied it. The work of Ostwald, Svedberg, Langmuir, Debye, and other colloid stalwarts, plus that of their scientific descendants, was largely sidestepped. Sooner or later, I predict, supramolecular chemistry will exploit more fully reflectometry, small angle neutron scattering, small-angle x-ray scattering, ellipsometry, tensiometry, pulse-gradient spin-echo NMR, light scattering, phase diagrams, and the many other tools of the colloid chemist. Supramolecular chemistry and colloid chemistry will, at that point, join hands and the rather artificial distinction will disappear. F.M. Menger, PNAS, 2002, 98, 4818, Emory University Langmuir, J. Colloid and Interface Sci. Colloid and Surface, A, B Thin Solid Films Colloid and Polymer Sciences J. Dispersion Sci. Advances in Colloid and Surfaces Current opinion in Colloid and Interface 与胶体与界面相关的学术杂志 Langmuir Film Langmuir-Blodgett Layer-by-Layer (LbL) Self-Assembled Monolayer (SAM) Langmuir 单分子膜 Bolaamphiphile Gemini Non-amphiphile 界面组装体