CeZrYLa＋LaAl催化剂用于理论空燃比天然气汽车尾气净化.pdfVIP

ChineseJournalofCatalysis36(2015]290—298 催化学报2015年 第36卷 第3期 Ivcvcw．chxb．cn a鑫¨曩 I w w 零in霉dir蕞l ． · n i jOUraIbom霉 赢嚣黟 wwel i¨ ／IQ 霹童e／羹b ：j蠡 Article CatalyticperformanceofPt-Rh／CeZrYLa+LaA1withstoichiometric naturalgasvehiclesem issions HongyanShang，YunWangb，YajuanCuicRuimeiFang，WeiHuaMaochuGongd YaoqiangChen ，d， aCollegeofChemicalEngineering,SichuanUniversity,Chengdu610065,Sichun,China bSichuanZhongziExhaustGasCleaningCo Ltd．，Chengdu611731Sichuan,China CollegeofArchitectureandEnvironment,SichuanUniversiyt, engdu610065,Sichuan,China dKeyLaboratoryofGreenChemistry＆TechnologyofMinistryofEducation,CollegeofChemistry,SichuanUniversity,Chengdu610064,Sichun,China A R T IC L E lN F 0 A B S T R A C T Articlehtory： ThecompositesupportCeZrYLa+LaAlwaspreparedbyaco—precipitationmethod．andPt—Rhbime— Received19October2014 talliccatalystswerefabricatedonthissupportusingdifferentpreparationprocedures．Thecarolytic Accepted12December2014 activitiesofthesematerialsweretestedinagasmixturesimulatingtheexhaustfrom astoichio— Published20March2015 metricnaturalgasvehicle．Theas-preparedcatalystswerealsocharacterizedbyX—rayphotoelec- tron spectroscopy,X-ray difiraction，N2adsorption-desorption andH2。grammed reduction．ItwasfoundthattheorderofactivitiesforCH4,COandNOconversionwasCat3≈Cat2 Keywords： Cat1，whereCat3hadthelowestlight—offtemperature(0]forCO(114。c)andNO(149。c)，the Platium-rhodium NanocompositeCeZrYLa+LaAl lowestcompleteconversiontemperature(0]forcH4(398。c)andCO(