甲醛和铁粉协同还原浸出低品位氧化锰矿.docVIP

甲醛和铁粉协同还原浸出低品位氧化锰矿 卢友志1，马华菊2，陈东莲2，明宪权3，李维健3，袁爱群1，韦冬萍1，唐雅芳1 (1.广西民族大学 化学化工学院化学与生物转化过程新技术重点实验室南宁 530006； 2.桂林理工大学南宁分校南宁 530001；3.中信大锰矿业有限责任公司，南宁 530022) 摘要：以甲醛和铁粉为还原剂在硫酸溶液中协同还原氧化锰矿，考察了还原剂用量、硫酸体积分数、浸出时间、浸出温度、液固比和搅拌速率对锰浸出率、浸出液中铁和甲酸的质量浓度的影响，并用响应面法设计优化试验。结果表明硫酸的体积分数为15%甲醛用量为理论量的90%甲醛和铁的为2二者浸出时间之比为2总浸出时间2.93 h浸出温度85 ℃液固比6速150 r/min，锰浸出率达98.04%，浸出液中铁和甲酸的质量浓度分别为13.96 mg/m、1.4mg/mL。 关键词：甲醛；铁粉；氧化锰矿 中图分类号：TF803.2 文献标志码：A 文章编号：1007-7545（2015）10-0000-00 Synergic Reductive Leaching of Manganese from Low-grade Oxide anganese Ore with Formaldehyde and Iron Powder LU You-zhi1, MA Hua-ju2, CHEN Dong-lian2, MING Xian-quan3, LI Wei-jian3, YUAN Ai-qun1, WEI Dong-ping1, TNAG Ya-fang1 (1. School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Key Laboratory of New Technology of Chemical and Biological Transformation Processes, Nanning 530006, China; 2. Guilin University of Technology at Nanning, Nanning 530001,China; 3. CITIC Dameng Mining Industries Limited, Nanning 530022, China) Abstract: Manganese oxide ores were synergic reductive leached in sulfuric acid medium with formaldehyde and iron powder as reductant. The effects of reductant dosage, volume fraction of sulfuric acid, reaction time, leaching temperature, ratio of liquid to solid (L/S), and stirring rate on manganese extraction rate, mass concentrations of iron and formic acid in lixivium were studied. Technology parameters were optimized by response surface methodology. The results show that manganese leaching rate is 98.04%, and mass concentrations of iron and formic acid in lixivium is 13.96 mg/mL and 1.40 mg/mL respectively under the optimum conditions including volume fraction of sulfuric acid of 15%, 90% of theoretical amount of formaldehyde, CH2O/Fe mole ratio of 2, reaction time ratio of 2, total leaching time of 2.93 h, leaching temperature of 85 ℃, L/S=6, and stirring rate of 150 r/min. Key words: formaldehyde; iron powder; manganese oxide ore; synergic leaching 低品位氧化锰矿的有效利用是解决目前我国锰消费增长