滑石粉等填充改高密度聚乙烯的性能研究.pdfVIP

ABSTRACT The main study includes: surface modification mechanism and token of the inorganic filler talc, CaCO3 and wollastonite; effect of fillers on properties of filled HDPE composite and co-composite. The surface modification of talc etc is treated .The effect of modification is evaluated by a serious of methods, including contact angle, activation rate and absorptioon of DOP. For the modified fillers, contact angles to distilled water are increased markedly, absorption of DOP are dereased, and activation rates are increased with increased coupling agent content. The results show that the modification change the polarity of the surface of fillers, the surface change from hydrophilic to hydrophobic. In order to discuss modification mechanism, we study the unmodified, modified fillers and coupling agnet by IR. The spectrograms of modified fillers distilled by acetone still show the character apices of coupling agents at 2850cm-1and 2920cm-1, which indicates the chemical bond effect between coupling agents and fillers surface. Modified fillers can be more contributing, decrease of absorption of DOP can reduce the immobility of plasticizing agent, so that decrease the cost. The modified poeder of better effect is respectively added as fillers to blend HDPE matrix, then manufacture HDPE composite by melt extrude. Study the mechanical properties, thermal properties and anti- aging properties, moreover SEM. The results show that : firatly ,talc, CaCO3 and wollastonite are activated by the coupling agent to improve the matrix resin wi