磁性纳米粒子负载钯催化有机合成反应研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc1109201 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 磁性纳米粒子负载钯催化有机合成反应研究进展 袁定重* 黄 斌 (东华理工大学材料科学与工程系 南昌 330013) 摘要 磁性纳米粒子负载钯催化的有机合成反应, 由于具有催化活性高, 催化剂在外加磁场作用下即可快速分离和重 复使用等特点, 已引起了人们的广泛关注. 综述了近年来磁性纳米粒子负载钯催化有机合成反应的研究进展, 载体包 括 Fe O 纳米粒子、有机小分子修饰的磁性纳米粒子、SiO 包覆的磁性纳米粒子、碳修饰磁性纳米粒子、羟基磷灰石 3 4 2 包覆的磁性纳米粒子和有机高分子修饰的磁性纳米粒子等. 关键词 有机合成反应; 磁性纳米粒子; 负载钯催化剂; 催化 Progress in Organic Synthesis Reactions Catalyzed by Palladium Supported on Magnetic Nanoparticles Yuan, Dingzhong* Huang, Bin (Department of Materials Science and Engineering, East China Institute of Technology, Nanchang 330013) Abstract The organic synthesis reactions catalyzed by palladium supported on magnetic nanoparticles have attracted con- sideralbe attention because catalytic activity is excellent and supported catalyst can be separated easily with an external mag- net and reused several times. In this paper, the advances in the organic synthesis reactions catalyzed by palladium supported on magnetic nanoparticles have been reviewed. Fe O nanoparticles, organic small molecles modified Fe O nanoparticles, SiO 3 4 3 4 2 modified Fe O nanoparticles, carbon modified magnetic nanopartilces, hydroxyapatite modified magnetic nanopartilces and 3 4 polymer modified magnetic nanopartilces were used to support the palla