一点红地上部分的化学成分研究.pdfVIP

Chemical constituents from the aerial parts of Emilia sonchifolia 1 1 1 1 SHEN Shoumao , ZHANG Jing , LI Guangzhi , SHEN Liangang 1∗ 2 2 SI Jianyong , LIU Chunming , LU Hui 1. Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences, Peking Union Medical College, Beijing 100193, China 2. Guangxi Huahong Pharmaceutical Co. Ltd., Liuzhou 545007, China [ABSTRACT] AIM: To study the chemical constituents in the aerial parts of Emilia sonchifolia. METHODS: The compounds were isolated and purified by various chromatographic techniques and their structures were identified by spectroscopic methods including IR, NMR, HR-ESI-MS and X-ray diffraction. RESULTS: Thirty compounds were obtained and identified as 2-{4-hydroxy-7-oxabicyclo [2.2.1] heptanyl}-acetic acid (1), 2-(1,4-dihydroxy cyclohexanyl)-acetic acid (2), succinic acid (3), fumaric acid (4), p -hydroxybenzoic acid (5), 4-hydroxy isophthalic acid (6), 3,4-dihydroxycinnamic acid (7), 3,4-dihydroxy-benzeneacetic acid (8), methyl 4-hydroxybenzeneacetate (9), rhamnetin (10), isorhamnetin (11), quercetin (12), luteolin (13), tricin 7-O-β-D-glucopyranoside (14), 8-(2′′-pyrrolidinone-5′′-yl)-quercetin (15), 5,2′,6′-trihydroxy-7,8-dimethoxyflavone 2′-O-β-D-glucopyranoside (16), isorhamnetin 3-O-α-L-rhamnopyranoside (17), afzelin (18), quercetin 7-O-α-L-rhamnopyranoside (19), 5,2′,6′-trihydroxy-7-methoxyflavone 2′-O-β-D-glucopyranoside (20), quercetin 3-O-α-L-rhamnopyranoside (21), diosmin (22), isorhamnetin 3-O-rutinoside (23), vicenin-2 (24), esculetin (25), isowedelolactone (26), brev