缓_控释肥料纳米-亚微米级胶结包膜复合材料的制备与表征.pdfVIP

中国农业科学 2006,39(8):1598-1604 Scientia Agricultura Sinica 缓/控释肥料纳米-亚微米级胶结包膜复合材料的制备与表征 1,2 1,2 2 2 2 2 2 刘秀梅 ，冯兆滨 ，张树清 ，张夫道 ，张建峰 ，肖 强 ，王玉军 1 2 （江西省农业科学院土壤肥料研究所，南昌 330200； 中国农业科学院农业资源与农业区划研究所，北京 100081） 摘要：【目的】以天然高岭土和废弃泡沫塑料为原料，制备高岭土和塑料-淀粉的纳米-亚微米级复合材料， 用来作缓/控释肥料的胶结剂和包膜剂。【方法】采用有机物质插层复合、微乳化和高剪切方法制备了高岭土和塑 料-淀粉的纳米-亚微米级复合材料，并通过扫描电镜、X-射线衍射、红外光谱和激光粒度分析对复合材料进行了 测试和表征。【结果】（1）有机物质插入了高岭土的层间，天然高岭土被剥离成纳米尺寸的片状结构，有机物质和 高岭土层间的水合羟基形成氢键连接；（2）塑料-淀粉纳米-亚微米级复合材料表面存在 10～20 nm 左右大小不一 的皱褶或孔径。【结论】此2 种复合材料可用来作缓/控释肥料的胶结剂和包膜剂。 关键词：缓／控释肥料；纳米-亚微米级复合材料；制备；表征 Preparation and Testing of Cementing and Coating Nano-subnanocomposites of Slow- or Controlled-release Fertilizer 1,2 1,2 2 2 2 LIU Xiu-mei , FENG Zhao-bin , ZHANG Shu-qing , ZHANG Fu-dao , ZHANG Jian-feng , 2 2 XIAO Qiang , WANG Yu-jun 1 (Soil and Fertilizer Institute, Jiangxi Academy of Agricultural Sciences, Nanchang 330200; 2 Institute of Agricultural Resources and Regional Planing, Chinese Academy of Agricultural Sciences, Beijing 100081) Abstract: 【Objective 】To select the cementing and coating agents of slow-or controlled-release fertilizer. 【Method 】 The natural kaoline and abandoned foam plastics were used to prepare nano-subnanocomposites using the methods of organic material intercalation, emulsification, and cut at high velocity. Besides, two kinds of nano-subnanocomposites were tested via several instruments including