Popescu法对煤燃烧反应机理的研究.pdfVIP

26 卷 15 期 中 国 电 机 工 程 学 报 Vol.26 No.15 Aug. 2006 2006 年8 月 Proceedings of the CSEE 2006 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 （2006 ）15-0068-05 中图分类号：O643 文献标识码：A 学科分类号：47010 利用Popescu法对煤燃烧反应机理的研究 张保生, 刘建忠, 周俊虎, 冯展管, 岑可法 （浙江大学，浙江省杭州市 310027 ） Popescu Method for Combustion Kinetic Mechanisms of Coals ZHANG Bao-sheng, LIU Jian-zhong, ZHOU Jun-hu, FENG Zhan-guan, CEN Ke-fa ( Zheji ang University, Hangzhou 310027, Zheji ang Province, China) ABSTRACT: Popescu Method is applied to analyze the da dT (1 b ) k (T) f (a ) ( 1) combustion kinetic mechanisms of two kinds of bituminous 其中：a为转化百分率；b为升温速率；f (a)为反应 coal and two kinds of anthracite coal, and twelve kinds of the 机理函数，表示反应速率 da/dT 与转化率a之间所 reaction mechanism are investigated. The results show that the combustion of bituminites is controlled by the three- 遵循的函数关系；k(T)为速率常数，与温度的关系 dimensional diffusion model and the anti Jander equation is the 通常认为符合Arrhenius 公式[2-3] most probable kinetic function, and that the combustion of k A exp ( E RT ) (2) anthracites is in according with the shrinking cylinder 式中：E 为活化能；A 为指前因子。 mechanism with surface reaction rate controlling. If a unified model is needed for the combustion of bituminite and anthracite, 将Arrhenius 公式代入式( 1)可得 the three-dimensional diffusion model controlled by the anti da dT (A b ) exp(E RT ) f (a ) (3) Jander equation is the best. The reaction order model employed 动力学研究的目的就在于求解能描述此反应的