CaCO3对NH3氧化的影响.pdfVIP

第31 卷 第35 期 中 国 电 机 工 程 学 报 Vol.31 No.35 Dec.15, 2011 2011 年12 月15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 35 文章编号：0258-8013 (2011) 35-0035-06 中图分类号：TK 16 文献标志码：A 学科分类号：470·20 CaCO 对 NH 氧化的影响 3 3 唐君实，宋蔷，吴兴远，付世龙，姚强 (清华大学热科学与动力工程教育部重点实验室，北京市 海淀区 100084) Influence of CaCO on NH Oxidation 3 3 TANG Junshi, SONG Qiang, WU Xingyuan, FU Shilong, YAO Qiang (key Laboratory of Thermal Science and Power Engineering of Ministry of Education, Tsinghua Universiy, Haidian District, Beijing 100084, China) ABSTRACT: CaCO3 influence selective non-catalytic 0 引言 reduction (SNCR) performance. This paper studied the influence of CaCO3 on NH3 oxidation. Experiments were 我国以煤炭为主的能源供应和消费格局在今 carried out in a fixed bed reactor. Influences of temperature 后相当长一段时间内不会改变，对煤碳利用过程中 (650-850 −6 −6 ℃), NH concentration (100 × 10 -1 500 × 10 ) and 产生的氮氧化物(NO ) 进行控制对于保护我国环 3 x O2 concentration (0-4%) on NH3 catalytic oxidation were 境，促进我国经济的可持续发展具有重要意义[1] 。 studied. Fourier transform infrared spectroscopy (FTIR) was 在各种NOx 控制技术中，选择性催化还原法[2-3] used to test NH3 and NO concentrations. It was proved that CaCO could catalyze NH oxidation. NH conversion and NO (selective catalytic reduction，SCR)和选择性非催化 3 3 3 selectivity would decrease when NH3 concentration in