助剂对CaSO4载氧体化学链燃烧的影响.pdfVIP

第 31 卷 第 5 期 中 国 电 机 工 程 学 报 Vol.31 No.5 Feb.15, 2011 40 2011 年 2 月 15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 0258-8013 (2011) 05-0040-08 T 546 A 470 10 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 助剂对 CaSO 载氧体化学链燃烧的影响 4 丁宁，郑瑛，罗聪，郑楚光 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Effect of Additives on CaSO Oxygen Carrier in Chemical-looping Combustion 4 DING Ning, ZHENG Ying, LUO Cong, ZHENG Chuguang (State Key Laboratory of Coal Combustion ( Huazhong University of Science and Technology), Wuhan 430074, Hubei Province, China) ABSTRACT: The experimental research was carried on the 关键词：化学链燃烧；复合载氧体；硫酸钙；助剂；硫释放 fixed bed reactor, investigating the reactions between gaseous 0 引言 fuel and oxygen carriers, which were made by impregnating CaSO4 with additives. The results indicate that additives can 化学链燃烧(chemical-looping combustion，CLC) greatly improve the activity of CaSO and shorten the reaction [1-5] 4 是一种新型的燃烧技术 ，它不直接使用空气中的 time. The conversion rates of all compound oxygen carriers are 氧分子，而是使用氧化物中的氧原子完成燃料的燃 more than 95% at 950 ℃. The curves of sulfur dioxide show 烧过程，避免燃料与空气的直接接触。载氧体主要 single peak characteristic, and obvious increase with 分