生物油轻组分的催化氢化与酯化-中国科技论文在线.pdfVIP

第5卷 第3期 2010 年 3 月 中国科技论文在线 Sciencepaper Online 217 生物油轻组分的催化氢化与酯化 阮仁祥，李文志，张 颖，朱锡锋 （中国科学技术大学安徽省生物质洁净能源重点实验室，合肥 230023 ） 摘 要：将生物油与一定量的甘油混合辅助蒸馏可以把生物油分成轻组分与重组分，根据轻重组分间性质的差异分别 进行精炼处理是一种非常有前景的方案。探讨了在 180 ℃，Pd/HZSM催化下不同还原介质对生物油轻组分催化加氢与 酯化的效果。生物油轻组分主要含有酸类、醛酮、不饱和醇及少量酚类化合物。精炼处理后，生物油轻组分中的有机 酸普遍转化为酯类化合物，糠醛被完全消除。其中甲酸与甲酸钠引发的水煤气反应能够提供大量H ,可以取代H 作为 2 2 还原介质。 关键词：生物油轻组分；Pd/HZSM ；催化加氢；酯化 中图分类号：TK6 文献标志码：A 文章编号：1673－7180(2010)03 －0217 －7 Experimental research on catalytic hydrogenation and esterification of light fraction of bio-oil Ruan Renxiang ，Li Wenzhi ，Zhang Ying ，Zhu Xifeng (Anhui Province Key Laboratory of Biomass Clean Energy , University of Science and Technology of China, Hefei 230023, China) Abstract: Distilled bio-oil with a certain mount of glycerol could divide bio-oil into two groups (light fraction and heavy fraction). Due to the different character of the two groups, it is a reasonable way to upgrading them respectively. In this paper, the effect of different reducing mediums on light fraction of bio-oil had been investigated under 180 ℃ using Pd/HZSM as catalyst. The light fraction of bio-oil contained acids, aldehydes, ketones, unsaturated alcohols and some phenols. The results showed that most organic acids were transformed into esters and furfurals were eliminated. Formic acid and sodium formate could function as effective reducing medium by supplying H2 through water-gas shift reaction. Key words: light fraction of bio-oil ；Pd/HZSM ；catalytic hydrotreating ；esterification 随着石油天然气等化石能源的日益枯竭，开发新的 处理才能进一步的使用。目前，