原位合成无表面活性剂纳米钯用于催化氢转移反应合成偶氮类化合物及对不饱和双键的还原.pdfVIP

Chinese Journal of Catalysis 34 (2013) 2084–2088 催化学报 2013年 第34卷 第11期 |   a v a i l a b l e  a t  w w w . s c i e n c e d i r e c t . c o m   j o u r n a l  h o m e p a g e :  w w w . e l s e v i e r . c o m / l o c a t e / c h n j c   Article (Dedicated to Professor Yi Chen on the occasion of his 80th birthday)  Synthesis of in‐situ surfactant‐free Pd nanoparticle catalysts for the synthesis of aromatic azo compounds and for unsaturated bond hydrogenation by hydrogen transfer † † Xin Wang , Jiaqing Wang , Fenqiang Qi, Lei Hu, Xinming Li, Xueqin Cao, Hongwei Gu* Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, China   A R T I C L E I N F O A B S T R A C T Article history: We developed a simple and efficient method to synthesize aromatic azos by hydrogen transfer using Received 19 June 2013 palladium(II) acetylacetonate as a catalyst and isopropyl alcohol as a hydrogen source. Further‐ Accepted 22 July 2013 more, this system also showed catalytic potential for the hyd