尿素法合成Cu2+-Ni2+-Fe3+-LDHs 毕业论文.doc

尿素法合成Cu2+-Ni2+-Fe3+-LDHs 摘 要 类水滑石 (LDHs)化合物是一类典型的阴离子型层状材料。LDHs的构筑单元和结构的可控性和多样性，为此类材料的应用研究提供了广阔前景。近年来以水滑石结构为前驱物制备复合氧化物的途径越来越引起人们的重视。水滑石具有的特殊结构使它们作为新型催化材料表现出了很多优异的性能，在吸附、离子交换、催化以及光、电、磁等方面都表现出巨大潜力和诱人前景本文Cu2+-Ni2+-Fe3+-LDHs，以CuCl2?2H2O、NiCl2?6H2O、FeCl3?6H2O为原料，°C下连续反应8h，并沉化24h，成功地制备出了高结晶性的Cu2+-Ni2+-Fe3+-LDHs材料。实验结果表明，该新型材料具有低比表面积和较好的层状结构，它是一种新型的高结晶性的功能型催化剂材料。 关键词：Cu2+-Ni2+-Fe3+-LDHsABSTRACT Hydrotalcite-like compounds, also known as layered double hydroxides (LDHs) , are one kind of typical anionic layered materials。The host hydroxide layers were orderly combined with guest molecules by electrostatic, hydrogen bonding and V uder waals interaction。 The control ability and diversity of the LDHs building units open up wide prospects for their application research。The way to derive composite oxides by hydrotalcite compound abstracts scientists eyes。Because of their special structure，LDHs composites attract much attention because of their prospective applications in absorption、ion-exchange、catalyzing、 light、electricity and magnetic, fields，they have exhibited excellent properties as a new type of catalytic materials and received much attention。 In this paper, Cu2+-Ni2+-Fe3+-LDHs materials is synthesized by using urea way ,is taken from the CuCl2?2H2O、NiCl2?6H2O 、FeCl3?6H2O as a raw materials , complex-agent is sodium tartaric, precipitator is urea, under degree Celsius consecutive reaction eight hours, and chemical deposit twenty-four hours, and was succeed manufactured high crystallize Cu2+-Ni2+-Fe3+-LDHs materials。The experimental results showed that the new material had a relative small BET surface area and good layer structure, is a kind of new pattern high crystallize function catalyst material。Key words：Cu2+-Ni2+-Fe3+-LDHs；crystallize；Urea；Sodium tartaric Thesis：Experimental Research 1 前言 1 1.1 LDHs的基本结构...............................................................................................1 1.2 LDHs的性质 2 1.2.1 碱性........................................