《Voltammetric studies of electrochemical pretreatment of rotating-disc glassy carbon electrodes in phosphate buffer》.ppt

Voltammetric studies of electrochemical pretreatment of rotating-disc glassy carbon electrodes in phosphate buffer Journal of Electroanalytical Chemistry 419 (I996) 7- 14 IF 2.729 Content Rotating-disc glassy carbon Inexpensiveness Wide potential window Ease of surface modification Reproducibility of the electrochemical activity of glassy carbon electrode Mechanical polishing Ultrasonic cleaning Vacuum heating Electric arc activation Laser irradiation Electrochemical activation Experimental Conclusion 1 All three of these redox processes were pH dependent 2 The peak potentials shifted negatively with increasing pH values 3 The involvement of hydrogen ions in all these processes. 4 Two anodic peaks are related to the oxygen containing functional groups 5The products of these redox reactions were surface-bound. Reporter： Xiong Tianhao Date：2016.01.07 Email:xt Literature Reports 东华理工大学化学生物与材料科学学院 Faculty of Biology, Chemistry and Material Science, East China University of Technology Background 1 Experimental 2 Results and Discussions 3 Conclusion 4 Background 0.1 M Phosphoric acid pH2 0.1 M phosphate acid pH3 pH4 pH5 pH6 pH7 pH8 Threeelectrode arrangement Glassy carbon electrode Platinum foil electrode KCl saturated calomel electrode 5.0mm diameter Al2O3 Results and Discussions Fig. 1. Cyclic voltammogram of a freshly polished and cleaned rotatingdisc glassy carbon electrode in phosphate buffer at pH3.0. Scan rate I00 mV s-1 ‘. Note: the anodic current is negative here and in subsequent figs. Fig. 2. Cyclic voltammogram of a bare glassy carbon electrode in phosphate buffer at pH3.0 when the potential was cycled between + 2.3 and - 1.2V. Scan rate I00 mV s-1 . Peak potentials quoted vs. SCE. Numbers in parentheses correspond to the solution pH at measurement. Fig. 3. Cyclic voltammogram of the rotating glassy carbon electrode at pH8.0 under identical experimental conditions to Fig. 2. Fig. 4. Magnified portion of the reduction waveforms obtained dur